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A novel preparation of methyl ketones through one-carbon homologation of aldehydes |
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| Authors: | Lei Wang Pinhua LiJincan Yan Zhongzhi Wu |
| Institution: | a Department of Chemistry, Huaibei Coal Teachers College, Huaibei, Anhui 235000, PR China b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, PR China c Department of Chemistry, The University of Tennessee, Knoxville, TN 37996-1600, USA |
| Abstract: | A novel two-step aldehyde homologation procedure for the preparation of methyl ketones has been developed, which involves the use of 1,1-dibromo-1-alkenes as precursors and zinc metal as mediator in near-critical water. |
| Keywords: | 1 1-dibromo-1-alkene near-critical water zinc metal homologation methyl ketone aldehyde |
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