ZrCl4 as a mild and efficient catalyst for the one-pot conversion of TBS and THP ethers to acetates |
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| Authors: | Ch.Sanjeeva Reddy G SmithaS Chandrasekhar |
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| Affiliation: | a Department of Chemistry, Kakatiya University, Warangal-506009, India
b Indian Institute of Chemical Technology, Hyderabad-500007, India |
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| Abstract: | A mild, efficient and chemoselective method has been developed for the direct transformation of tert-butyldimethylsilyl and tetrahydropyranyl protected alcohols into the corresponding acetates with acetic anhydride and zirconium(IV) chloride as the catalyst in acetonitrile, in a one-pot reaction with high yields and short reaction times. This method has been applied to a variety of substrates. |
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| Keywords: | zirconium(IV) chloride one-pot reaction |
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