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Redox-switchable π-conjugated systems bearing terminal ruthenium(II) complexes |
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| Authors: | Xiuliang ShenToshiyuki Moriuchi Toshikazu Hirao |
| Institution: | Department of Materials Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan |
| Abstract: | p-Phenylenediamine bearing terminal bipyridyl moieties was synthesized by palladium-catalyzed amination. The corresponding ruthenium(II) complex was formed and characterized, providing a redox-switchable photoinduced electron-transfer system. |
| Keywords: | π-conjugated ligand redox-active spacer bipyridyl ruthenium(II) complex photoinduced electron transfer |
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