Highly regioselective rhodium(II)-catalysed carbenoid insertion reaction into sp CH bond: a general method for the synthesis of 3,3a-dihydro-2H,5H-pyrrolo[1,2-a]quinoline-1,4-dione ring system |
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Authors: | Pranab HaldarGandhi K Kar Jayanta K Ray |
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Institution: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721302, India |
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Abstract: | A simple and high yielding general method for the synthesis of 3,3a-dihydro-2H,5H-pyrrolo1,2-a]quinoline-1,4-dione derivatives through a highly regioselective rhodium(II)-catalysed carbenoid sp2 C-H insertion reaction on suitably substituted γ-lactam diazocarbonyl compounds is described. |
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