Rhodium-catalyzed cycloisomerization of allenenes via metalacycle intermediates |
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| Authors: | Tatsuya MakinoKenji Itoh |
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| Institution: | Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan |
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| Abstract: | In the presence of a catalytic amount of the rhodium complex, allenenes undergo cycloisomerization reactions to result in the selective formation of five and seven membered exo-alkylidenecarbocycles and heterocycles via novel exo-alkylidenerhodacyclopentane intermediates. |
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