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A new method for the preparation of peroxyacetic acid using solid superacid catalysts
Authors:Madhu Sudan SahaYoshinori Nishiki  Tsuneto FurutaAo Denggerile  Takeo Ohsaka
Affiliation:a Development Department, Permelec Electrode Ltd, 2023-15 Endo, Fujisawa-city, Kanagawa 252-0816, Japan
b Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan
Abstract:A new method for the preparation of peroxyacetic acid from acetic acid and hydrogen peroxide in the presence of solid superacids as a catalyst under mild conditions has been proposed. The preparation of peroxyacetic acid could be carried out in a batchwise operation as well as in a flow-system operation. Nafion-H was found to be active and very stable catalyst for the preparation of peroxyacetic acid and to be regenerated without the loss of catalytic activity.
Keywords:peroxyacetic acid   acetic acid   solid superacid   Nafion-H
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