A facile synthesis of 1,2-oxaphospholenes and stereoselective conversion into oxaphospholanes |
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| Authors: | Jung Hwan HahBum Sung Lee Shi Yong LeeHee-Yoon Lee |
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| Institution: | Center for Molecular Design and Synthesis, Department of Chemistry & BK21 School of Molecular Science, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Republic of Korea |
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| Abstract: | Treatment of α-acylallylphosphonates with m-CPBA in the presence of MgSO4, afforded 1,2-oxaphosphol-3-enes 2-oxides and the subsequent cuprate addition produced 1,2-oxaphospholanes stereoselectively. |
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