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Efficient construction of bicyclic systems by an internal SN2′ enolate alkylation/ring-closing metathesis (RCM) strategy: a concise synthesis of the trans-hydrindane nucleus |
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| Authors: | Hyunil JoJongkook Lee Hyoungsu KimSanghee Kim Deukjoon Kim |
| Institution: | a Research Institute of Pharmaceutical Sciences, College of Pharmacy, Seoul National University, San 56-1, Shinrim-Dong, Kwanak-Ku, Seoul 151-742, South Korea b Natural Products Research Institute, College of Pharmacy, Seoul National University, 28 Yungun, Jongro-Ku, Seoul 110-460, South Korea |
| Abstract: | A concise and efficient synthesis of the trans-hydrindane system has been achieved by a novel intramolecular SN2′ enolate alkylation/ring-closing metathesis (RCM) strategy with a good degree of stereocontrol. |
| Keywords: | trans-hydrindane SN2&prime enolate alkylation ring-closing metathesis (RCM) |
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