Thermal relaxation in excited electronic states of d and d metal complexes |
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Authors: | Leslie S Forster |
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Affiliation: | Department of Chemistry, University of Arizona, Tucson, AZ 85721, USA |
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Abstract: | Photophysical kinetic results have played an important role in assessing excited state relaxation pathways in transition metal complexes. The applicability of a kinetic analysis is critically dependent on the quality of the individual decay rates, the temperature range examined, and the model used to extract the activation parameters. The extensive literature describing the temperature dependence of excited state depopulation in d3 and d6 complexes permits an evaluation of both the power and limitations of kinetic arguments in assessing the mechanism of excited state relaxation. |
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Keywords: | Transition metal complexes Photophysics Temperature dependence of decay rates Environmental mobility and heterogeneity |
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