Solid state thermal isomerisation of diethylenetriamine complexes of NiX2 (X=NO3, ClO4, BF4 and CF3SO3) |
| |
Authors: | Subratanath Koner Ashutosh Ghosh Nirmalendu Ray Chaudhuri |
| |
Institution: | (1) Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 700 032 Calcutta, India |
| |
Abstract: | Summary Ni(dien)2]X2·nH2O (dien=diethylenetriamine; n=0, X=NO3 or CF3SO3; n=0.5, X=ClO4 or BF4 and n=2, X=CF3SO3) complexes have been prepared and investigated thermally in the solid state. Ni(dien)2](NO3)2 (1) and Ni(dien)2](CF3SO3)2 (2) undergo endothermic irreversible phase transitions (209–247°C and 184–205°C; H=5.6 kJ mol–1 and 7.7 kJ mol–1 for (1) and (2), respectively). Ni(dien)2](ClO4)2·0.5H2O (3) shows an endothermic irreversible phase transition after deaquation (201–216°C; H=7.7 kJ mol–1). Ni(dien)2](BF4)2·0.5H2O also shows an endothermic irreversible phase transition after deaquation, accompanied by partial decomposition. All the complexes possess octahedral geometry with the ligands arranged meridionally. The phase transitions are explained in terms of conformational changes of the triamine chelate rings.Author to whom all correspondence should be directed. Supplementary data available: i.r. spectra (Table 4) and x-ray diffraction patterns (Table 5). |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|