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Thermodynamic Properties of Salsoline Salsolinodithiocarbamate
Authors:B K Kasenov  Zh K Tukhmetova  Sh B Kasenova  S M Adekenov  A M Gazaliev  S D Fazylov  A Nukhuly  A V Boldashevskii
Institution:(1) Institute of Phytochemistry, Ministry of Education and Science of the Republic of Kazakhstan, Karaganda, Kazakhstan;(2) Institute of Organic Synthesis and Coal Fuel Chemistry, Karaganda, Kazakhstan;(3) Pavlodar State University, Pavlodar, Kazakhstan
Abstract:Heat of solution of salsoline salsolinodithiocarbamate (SS) at 1 : 18 000, 1 : 36 000, and 1 : 72 000 dilution (mol per mol H2O) was determined on a DAK-I-IA calorimeter, and the standard heat of solution at infinite dilution was estimated. The temperature dependence of the heat capacity of SS was studied over the range 173–348 K. The heats of combustion and fusion, and the standard heat of formation of liquid (molten) and crystalline SS were estimated by indirect methods.
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