New modified electrodes for the separate determination of anionic surfactants |
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Authors: | E. G. Kulapina V. A. Ovchinskii |
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Affiliation: | (1) Department of Chemistry, Saratov State University, ul. Astrakhanskaya 83, 410026 Saratov, Russia |
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Abstract: | Nylon, chitin, polyvinyl chloride, and polymethyl methacrylate molecular sieves with pores of various size are studied as membrane surface modifiers in electrodes reversible to anionic surfactants. A procedure for the synthesis of molecular sieves with pores of the specified size from water-insoluble polymeric matrix (polyvinyl chloride, polymethyl methacrylate) was developed. Different methods were proposed for modifying the electrode surface. It was demonstrated that modified electrodes provide the separate determination of alky 1 sulfates bearing alkyl radicals of different lengths (C12-C14). |
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