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Self-inclusion of proline-functionalised calix[4]arene leads to hydrogelation
Authors:Goh Ching Yong  Becker Thomas  Brown David H  Skelton Brian W  Jones Franca  Mocerino Mauro  Ogden Mark I
Affiliation:Nanochemistry Research Institute, Department of Chemistry, Curtin University, GPO Box U 1987, Perth, Australia 6845.
Abstract:Solution-phase and solid-state structural studies indicate that the remarkable hydrogelation properties of a proline-functionalised calix[4]arene emerge as a result of extended helical structures formed via inclusion of a proline moiety in a neighbouring calixarene cavity.
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