Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds |
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| Authors: | Beweries Torsten Hansen Sven Kessler Monty Klahn Marcus Rosenthal Uwe |
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| Institution: | Leibniz-Institut für Katalyse e. V. an der Universit?t Rostock, Albert-Einstein-Str. 29a, 18059, Rostock, Germany. |
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| Abstract: | Dehydrogenation of Me(2)NH·BH(3) (1) by group 4 metallocene alkyne complexes of the type Cp(2)M(L)(η(2)-Me(3)SiC(2)SiMe(3)) Cp = η(5)-cyclopentadienyl; M = Ti, no L (2Ti); M = Zr, L = pyridine (2Zr)] and group 4 metal amido complexes of the type M(NMe(2))(4) M = Ti (8Ti), Zr (8Zr)] is presented. |
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