Formation of Ga2Te2 and M3Te3(M = Ga, In) rings from reactions of sodium ditelluroimidodiphosphinate with Group 13 halides |
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| Authors: | Copsey May C Chivers Tristram |
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| Affiliation: | Department of Calgary, University of Calgary, Calgary, Alberta, CanadaT2N 1N4. |
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| Abstract: | Metathetical reactions of Na[N(iPr2PTe)2] with Group 13 metal halides produce the telluride complexes {Ga(mu-Te)[iPr2PNiPr2PTe]}2(2) and {M(mu-Te)[N(iPr2PTe)2]}3, M = In (3) and Ga (4), which contain central Ga2Te2 and M3Te3 rings, respectively. |
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