Branched poly(1,4‐butylene carbonate‐co‐terephthalate)s: LDPE‐like semicrystalline thermoplastics |
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| Authors: | Seong Yeon Park Jiseul Chun Jong Yeob Jeon Pyung Cheon Lee Yongtaek Hwang Bo Geun Song Rafael Ramos Chang Y. Ryu Bun Yeoul Lee |
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| Affiliation: | 1. Department of Molecular Science and Technology, Ajou University, Suwon, Korea;2. Catalyst Research Team 5th, Research Institute, Lotte Chemical Corporation, Daejeon, Korea;3. Department of Chemistry and Chemical Biology, Rensselaer Polytechnic Institute, Troy, New York |
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| Abstract: | Branched poly[1,4‐butylene carbonate‐co‐terephthalate]s (PBCTs) have been synthesized by the addition of a small amount of glycerol propoxylate ( 1 ) or pentaerythritol ( 2 ) in the polycondensation of 1,4‐butanediol, dimethyl carbonate, and dimethyl terephthalate. To avoid gel formation, the feed amount of 1 or 2 was carefully controlled at below 0.5 mol % for 1 and below 0.3 mol % for 2 . When feed of 1 or 2 was used, a high‐molecular weight melt state (Mw ～180,000 g/mol) was reached in a total reaction time of 5.5 to 6.5 h with a yield higher than 90%. The generated PBCTs were a semicrystalline polymer (Tg ～5 °C and Tm ～120 °C) when the terephthalate content (F[TPA]) was 45 to 50 mol %. The crystallization rate increased with increasing F[TPA] and branch content (F[ 1 or 2 ]); PBCT composed of F[TPA] = 49 mol % and F[ 1 ] = 0.44 mol % was crystallized completely in a short time, ～3 min, at a crystallization temperature of 50 °C. The branched PBCT exhibited more pronounced toughness in tensile test while providing the advantage of processibility at high shear rates due to the pronounced shear thinning in melt. It was also found that the branched PBCTs were biodegradable. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 914–923 |
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| Keywords: | biodegradable dimethyl carbonate polycondensation polycarbonates thermal properties |
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