New method for the synthesis of sym- octahydroxanthenes and sym- octahydrothioxanthenes |
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Authors: | V G Kharchenko A F Blinokhvatov |
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Institution: | (1) N. G. Chernyshevskii Saratov State University, 410601 Saratov |
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Abstract: | -Ketols formed as a result of intramolecular cyclization of 1,5-diketones by alkaline condensation of aldehydes with ketones are converted to 9-R-sym-octahydroxanthenes by the action of acids. Treatment of the -ketols with acids in the presence of hydrogen sulfide leads to the corresponding 9-R-sym-octahydrothioxanthenes. The spectral characteristics of the compounds obtained are given, and some of their properties are described.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1615–1619, December, 1978. |
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