Solvent effects on the solubilities of reference electrolytes |
| |
| Authors: | M. Pirklbauer G. Gritzner |
| |
| Affiliation: | (1) Institut für Chemische Technologie Anorganischer Stoffe, Johannes Kepler Universität, A-4040 Linz, Austria |
| |
| Abstract: | Solubilities of bis(biphenyl)chromium(I) tetraphenylborate were measured in 25, solubilities of tetraphenylarsonium tetraphenylborate in nine and solubilities of bis(biphenyl)chromium(0) in seven nonaqueous solvents. Linear dependences of the pKs-values for these compounds as well as the pKs values for tetraphenylstibonium tetraphenylborate, tetraphenylmethane and tetraphenylgermane were observed. The relations between the pKs-values of the above mentioned compounds and solvent parameters as well as solvent structure are discussed. |
| |
| Keywords: | Reference electrolytes solvent effects solubilities of bis(biphenyl)chromium tetraphenylborate, tetraphenylarsonium tetraphenylborate |
| 本文献已被 SpringerLink 等数据库收录！ |
