Approaches to the preparation of carborane-containing carbosilane compounds |
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Authors: | Núñez Rosario González Arántzazu Viñas Clara Teixidor Francesc Sillanpää Reijo Kivekäs Raikko |
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Institution: | Institut de Ciència de Materials de Barcelona (CSIC), Campus de la UAB, 08193 Bellaterra, Spain. |
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Abstract: | Structure: see text] A novel type of carborane cluster assembly has been successfully prepared using carbosilane derivatives as a scaffold. Two synthetic routes have been used: One involves the reaction of a carbosilane containing terminal Si-Cl functions with the lithium salt of the phenyl-o-carborane, and the second one consists of a highly efficient hydrosilylation of tetravinylsilane with the corresponding carboranylsilane. The crystal structure of this carborane-containing carbosilane compound has been determined by X-ray diffraction. |
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