A New On-fluorescent Probe for Manganese (II) Ion |
| |
Authors: | Kaku Dutta Ramesh Ch Deka Diganta Kumar Das |
| |
Institution: | 1. Department of Chemistry, Gauhati University, Guwahati, 781014, Assam, India 2. Department of Chemical Sciences, Tezpur University, Napaam, Tezpur, 784 028, Assam, India
|
| |
Abstract: | A new fluorescent probe for Mn2+ ion, (6E)-N-((E)-1,2-diphenyl-2-(pyridin-2-ylimino)ethylidene)pyridin-2-amine (L), has been synthesized from benzil and 2-amino pyridine and characterized. In 1:1 (v/v) CH3CN:H2O (pH 4.0, universal buffer) L exhibits fluorescent intensity with emission peak at λmax 360 nm on excitation with photons of 310 nm. Fluorescent intensity of L increases distinguishingly on interaction with Mn2+ ion compared to metal ions—Na+, K+, Ca2+, Mg2+, Ba2+, Fe2+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+, Hg2+, Pb2+ and Ag+ individually or all together. The enhancement in fluorescent intensity is due to snapping of photoinduced electron transfer (PET) prevailed in free L. Fluorescence and UV/visible spectral data analysis shows that binding stoichiometry between Mn2+ and L is 1:1 with log β?≈?3.0. Both L and its Mn2+ complex were optimised using density functional theory (DFT) and vibrational frequency calculations confirm that both are at local minima on the potential energy surfaces. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|