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Multilayer films of cationic surfactants incorporating polyoxometalate on electrodes
Authors:Yaqin Fu  Tierui Zhang  Changqing Sun
Institution:(1) Department of Chemistry, Jilin University, Changchun 130023, People's Republic of China,
Abstract:A new kind of multilayer of didodecyldimethylammonium bromide (DDAB) and 1:12 phosphomolybdic anions (PMo12) was achieved on the surface of a wax-impregnated graphite (WIG) electrode by ion exchange and electrostatic interaction. The characterization and electrochemical behavior of the multilayer films of DDAB/PMo12 is described in detail. The chemically modified electrode was shown to exhibit an excellent electrocatalytic activity toward the reduction of BrO3 anion in 0.5 M H2SO4 and possesses several attractive features, such as simple preparation, fast response, good stability, etc. Electronic Publication
Keywords:Multilayer films Phosphomolybdic acid Didodecyldimethylammonium bromide Chemically modified electrode Electrocatalysis
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