Reaction of perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine |
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| Authors: | G G Furin Yu V Gatilov I Yu Bagryanskaya E L Zhuzhgov |
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| Institution: | (1) N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Acad. Lavrent'eva, 630090 Novosibirsk, Russian Federation;(2) Novosibirsk State University, 2 ul. Pirogova, 630090 Novosibirsk, Russian Federation |
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| Abstract: | Reaction of perfluoro-2-methylpent-2-ene with ethylenediamine and hexamethylenediamine results in 9-fluoro-5,9-bis(pentafluoroethyl)-6,8,8-tris(trifluoromethyl)-1,4-diazabicyclo5.2.0]nona-4,6-diene,
whose structure was confirmed by X-ray analysis, and 11-pentafluoroethyl-10-trifluoromethyl-1,8-diazabicyclo7.2.0]undeca-8,10-diene,
respectively. The reaction pathways are discussed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1578–1582, August, 1999. |
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| Keywords: | nucleophilic substitution and addition cyclization perfluoro-2-methylpent-2-ene ethylenediamine hexamethylenediamine |
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