An improved strategy for the stereoselective synthesis of glycosides using glycosidases as catalysts |
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Authors: | Anne Baker Nicholas J. Turner Matthew C. Webberley |
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Affiliation: | Department of Chemistry, University of Exeter, Stocker Road, Exeter EX4 4QD U.K. |
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Abstract: | A alternative strategy for the synthesis of glycosides, using glycosidase enzymes, has been developed. In contrast to previous procedures, this new method uses limiting amounts of the acceptor alcohol substrate in combination with an excess of the glycosyl donor. Using this procedure, a series of mono- and disaccharides have been prepared. |
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