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穴醚[2.2.2]的HgCl_2,CdCl_2及Cd(NO_3)_2配合物的红外
引用本文:康经武,江天籁. 穴醚[2.2.2]的HgCl_2,CdCl_2及Cd(NO_3)_2配合物的红外[J]. 光谱学与光谱分析, 1995, 0(5)
作者姓名:康经武  江天籁
作者单位:中科院兰州化学物理所
摘    要:本文合成了穴醚[2.2.2]的HgCl2,CdCl2及Cd(NO3)2配合物,用元素分析数据确定了它们的化学组成,并对其红外和拉曼光谱进行了经验归属。基于这两组数据推测了配合物的结构。

关 键 词:穴醚[2.2.2],配位化合物,红外光谱,拉曼光谱

IR AND RAMAN SPECTRA OF COMPLEXES OF CRYPTAND [2. 2.2] WITH HgCI_2,CdCl2 AND Cd(NO_3)_2
KANG Jingwu and JIANG Tianlai. IR AND RAMAN SPECTRA OF COMPLEXES OF CRYPTAND [2. 2.2] WITH HgCI_2,CdCl2 AND Cd(NO_3)_2[J]. Spectroscopy and Spectral Analysis, 1995, 0(5)
Authors:KANG Jingwu and JIANG Tianlai
Abstract:In this paper, three solid complexes of MCl_2 (M=Hg2+, Cd2+) and Cd (NO_3)_2with cryptand [2. 2.2] have been prepared. The composition of each complex has been determined by elemental analysis. The IR and Raman spectra of these complexes were studied, and some characteristic bands were assigned. With these data, the structure of the complexes can be characterized.
Keywords:Cryptand [2. 2.2]  Complex  Infrared spectra  Raman spectra
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