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Potassium selective chromoionophores
Authors:Ian P Danks  Ian O Sutherland
Institution:(1) Department of Chemistry, The University of Liverpool, P.O. Box 147, L69 3BX Liverpool, UK
Abstract:The ionisable chromoionophores5 were synthesised from simple precursors. These chromoionophores extract alkali metal cations from aqueous solutions at pH > 7 into dichloromethane. The ratio of extraction coefficients for the chromoionophore5c for K+ and Na+ indicate that it has potential for use in optical fibre sensors for K+ in the presence of Na+, Mg2+ and Ca2+ at extracellular concentrations.This paper is dedicated to the memory of the late Dr C. J. Pedersen.
Keywords:Chromoionophores  potassium  hemispherand  optical fibre sensors
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