Electrochemical carboxylation with carbon dioxide |
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| Authors: | Hisanori Senboku Asahi Katayama |
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| Institution: | 1. Laboratory of Organic Synthesis, Division of Applied Chemistry, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan;2. Frontier Chemistry Center, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan;3. Graduate School of Chemical Sciences and Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan |
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| Abstract: | Studies carried out in the past two years on electrochemical fixation of carbon dioxide with carbon-carbon bond formation, so-called electrochemical carboxylation or electrocarboxylation, are reviewed. Among about twenty papers on electrochemical carboxylation published from 2014 to the present, recent advances in electrochemical carboxylation regarding asymmetric carboxylation, sacrificial anode-free carboxylation, and carboxylation following aryl radical cyclization are focused on and discussed. |
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| Keywords: | Electrochemical carboxylation Electrocarboxylation Carbon dioxide Carboxylic acid Sacrificial anode Carbon dioxide fixation |
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