Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80) |
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| Authors: | Wakahara Takatsugu Yamada Michio Takahashi Satomi Nakahodo Tsukasa Tsuchiya Takahiro Maeda Yutaka Akasaka Takeshi Kako Masahiro Yoza Kenji Horn Ernst Mizorogi Naomi Nagase Shigeru |
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| Institution: | Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan. |
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| Abstract: | The (139)La NMR study of the exohedrally functionalized derivatives of La(2)@C(80) metallofullerene, La(2)@C(80)(Ar(2)Si)(2)CH(2) (: Ar = Mes, Mes = mesityl, : Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C(80) cage. |
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