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Boundary conditions for ionotropic gelation of polyuronides |
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| Authors: | Evgenij E Braudo Vladimir P Yuryev |
| Abstract: | The determination of reagent concentrations sufficient for gelation in the course of a crosslinking reaction in solution enables characterization of macromolecular coil dimensions as a function of solvent quality and calculation of the apparent equilibrium constant and the reaction order with respect to polymer. Interactions of polyuronides with polycoordinative metal ions are discussed. |
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