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Functionalized liquid-crystalline polymers towards NLO-applications and piezo-sensors
Authors:Heinrich Kapitza  Holger Poths  Rudolf Zentel
Abstract:A systematic synthesis of functionalized 1c polymers is possible starting from precursor polymers with phenolic groups. The esterification of these precursor polymers with chiral acids proceeds nearly quantitatively and produces polymers with cholesteric and chiral smectic C* phases. A further functionalization of these polymers with “NLO-chromophores” produces polymers, which are suitable for second harmonic generation; a functionalization with crosslinkable groups leads to polymers, which act as piezoelements.
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