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Infrared spectrum of gaseous carbonyl fluoride-18O
Affiliation:1. Department of Chemistry, Faculty of Mathematics and Sciences, University of Indonesia, Kampus UI Depok, Jakarta 16424, Indonesia;2. Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama 223-8522, Japan;3. JST ACCEL, Yokohama 223-8522, Japan;1. National Research Council of Italy, Institute for Photonics and Nanotechnologies – Padova, Via Trasea 7, 35131, Padova, Italy;2. University of Padova, Department of Industrial Engineering, Via Marzolo 9, 35131, Padova, Italy;3. University of Padova, Department of Physics and Astronomy, Via Marzolo8, 35131, Padova, Italy;4. Italian Institute of Technology, Via Morego 30, 16163, Genova, Italy;5. University of Padova, Department of Information Engineering, Via Gradenigo 6/B, 35131, Padova, Italy;1. Lahore College for Women University, Lahore, Pakistan;2. Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, Pakistan;1. Electrochemistry Laboratory, Chemistry Group, National Metrology Institute, (TUBITAK UME), Kocaeli, Turkey;2. Department of Chemistry, Faculty of Arts and Sciences, Balıkesir University, Balıkesir, Turkey;1. Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, QLD 4072, Australia;2. Australian Institute of Innovative Materials, University of Wollongong, NSW 2500, Australia
Abstract:From the infrared spectra of gaseous carbonyl fluoride-18O(F122C18O) the six fundamental vibrational frequencies (in cm−1) are: (a1) 1895.2 (average of Fermi resonance doublet), 947.3, 576.5; (b1) 1242.3, 604.9; (b2) 770.0. These unambiguous assignments are consistent with the less certain assignments for this isotopic species that Mallinson, McKean, Holloway and Oxton, Spectrochim. Acta 31A, 143 (1975) derived from an argon-matrix spectrum of 4% F122 C18O in a mixture of four isotopomers.
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