| Abstract: | Further studies have been conducted on the condensation of electron-rich arenes or heteroarenes with the dienic system of phosphole P-complexes. According to the X-ray crystal structure analysis of one of the resulting 2-aryl-3-phospholene P-complexes, the condensation takes place on the side of the diene opposite to the complexing group. The decomplexation of the phospholene P–Mo(CO)5 and P–W(CO)5 complexes, respectively, by reaction with sulfur or halogens and tertiary amines yields the corresponding P-sulfides and oxides with full retention of the stereochemistry at phosphorus. Double condensation of the phosphole P-complexes onto the 2 and 5 positions of thiophene and furan ultimately leads to phosphole–thiophene–phosphole and phosphole–furan–phosphole chains. The first type has been characterized by X-ray crystal structure analysis of its P,P-disulfide. No electronic delocalization appears to take place along the chain. |
