| 烯丙基锂四氢呋喃配合物的合成 |
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| 引用本文： | 曹殿珍,李毅,许有龙,曾广赋,那玉贤,李英华,刘国智.烯丙基锂四氢呋喃配合物的合成[J].无机化学学报,1987,3(3):118-121. |
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| 作者姓名： | 曹殿珍 李毅 许有龙 曾广赋 那玉贤 李英华 刘国智 |
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| 作者单位： | 中国科学院长春应用化学研究所
(曹殿珍，李毅，许有龙，曾广赋，那玉贤，李英华)，中国科学院长春应用化学研究所(刘国智) |
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| 摘 要： | 在四氢呋喃存在下,将丙烯和丁基锂直接反应合成了未见文献报道的烯丙基锂四氢呋喃配合物。对产物组成进行了鉴定,并用红外光谱讨论了烯丙基的结构。对反应条件进行了较为详细的研究。
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| 关 键 词： | 烯丙基锂四氢呋喃配合物 |
| 收稿时间： | 1986/11/10 0:00:00 |
PREPARATION OF ALLYL LITHIUM THF COMPLEX |
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| Cao Dianzhen,Li Yi,Xu youlong,Zeng Guangfu,Na Yuxian,Li Yinghua and Liu Guozhi.PREPARATION OF ALLYL LITHIUM THF COMPLEX[J].Chinese Journal of Inorganic Chemistry,1987,3(3):118-121. |
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| Authors: | Cao Dianzhen Li Yi Xu youlong Zeng Guangfu Na Yuxian Li Yinghua and Liu Guozhi |
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| Institution: | Changchun institute of Applied Chemistry, Academia Sinica,Changchun institute of Applied Chemistry, Academia Sinica,Changchun institute of Applied Chemistry, Academia Sinica,Changchun institute of Applied Chemistry, Academia Sinica,Changchun institute of Applied Chemistry, Academia Sinica,Changchun institute of Applied Chemistry, Academia Sinica and Changchun institute of Applied Chemistry, Academia Sinica |
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| Abstract: | New allyl lithium THF complex was prepared conveniently by the reaction of propene with n-butyl lithium in the presence of tetrahydro-furan. The product was identified and its infrared absorption related to the structure of allyl group was discussed. The reaction conditions were studied in detail. |
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| Keywords: | allyl lithium tetrallydrofufan complex |
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