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铥配合物的红外有机电致发光
引用本文:洪自若,赵丹,梁春军,李锐钢,范镝,李文连.铥配合物的红外有机电致发光[J].发光学报,2000,21(2):177-178.
作者姓名:洪自若  赵丹  梁春军  李锐钢  范镝  李文连
作者单位:中国科学院长春光学精密机械及物理研究所,吉林,长春,130021
基金项目:“863”项目资助!(863-715-002-715)
摘    要:合成了两种三价铥配合物,并将其制成双层结构器件。首次得到了直流低压驱动下,来自铥离子^3H4→^3H6电子跃迁红外(IR)发光。

关 键 词:铥配保物  红外发光  电致发光  显示器
修稿时间:2000-01-30

Infrared Organic Electroluminescent Devices Based on Tm Complexes
HONG Zi-ruo,ZHAO Dan,LIANG Chun-jun,LI Rui-gang,FAN Di,LI Wen-lian.Infrared Organic Electroluminescent Devices Based on Tm Complexes[J].Chinese Journal of Luminescence,2000,21(2):177-178.
Authors:HONG Zi-ruo  ZHAO Dan  LIANG Chun-jun  LI Rui-gang  FAN Di  LI Wen-lian
Abstract:Two kinds of trivalent thulium ion complexes used for organic electroluminescent devices have been synthesized. IR emission spectrum from a bilayer structure device utilizing Tin complexes as emitting materials has been observed for the first time. It is clearly to draw the conclusion that the IR emission is ascribed to the electronic transition from 3H4 to 3H6 of Tm3+ ion chelated by ligands which possess higher energy level of lowest excited triplet state than the upper level 3H4. Intramolecular energy transfer should take place from ligands to central ion because of the absence of direct absorption of Tm3+ ion.
Keywords:Tin complexes  electroluminesc
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