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X-ray photoelectron and X-ray Auger electron spectroscopy studies of heavy ion irradiated C60 films
Authors:Amit Kumar  F. Singh  S.M. Shivaprasad  J.C. Pivin
Affiliation:a Institut NEEL, CNRS and Université Joseph Fourier, 25 rue des Martyrs, BP166, 38042 Grenoble Cedex 9, France
b Materials Science Division, Inter-University Accelerator Centre, Post Box 10502, New Delhi 110067, India
c Surface Physics and Nanostructures Group, National Physical Laboratory, New Delhi 110060, India
d Centre Spectrometrie Nucleaire et de Spectrometrie de Masse (CSNSM)-(IN2P3), Bâtiment 108, 91405 Orsay Campus, France
Abstract:The influence of 200 MeV Au ion irradiation on the surface properties of polycrystalline fullerene films has been investigated. The X-ray photoelectron and X-ray Auger electron spectroscopies are employed to study the ion-induced modification of the fullerene, near the surface region. The shift of C 1s core level and decrease in intensity of shake-up satellite were used to investigate the structural changes (like sp2 to sp3 conversion) and reduction of π electrons, respectively, under heavy ion irradiation. Further, X-ray Auger electron spectroscopy was employed to investigate hybridization conversion qualitatively as a function of ion fluence.
Keywords:Ion irradiation   Fullerene   X-ray photoelectron spectroscopy   X-ray-induced Auger electron spectroscopy
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