Insertions‐ und Substitutionsreaktion von Ameisensäuremethylester mit [Cp′2ZrCl(PHTipp)] – Molekülstruktur von meso‐trans‐[Cp′2ZrCl{OCH(PHTipp)2}] (Cp′ = η5‐C5MeH4, Tipp = 2,4,6‐Pri3C6H2) |
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Authors: | Ulrike Segerer Joachim Sieler Evamarie Hey‐Hawkins |
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Abstract: | Insertion and Substitution Reaction of Methyl Formate with Cp′2ZrCl(PHTipp)] – Molecular Structure of meso‐trans ‐Cp′2ZrCl{OCH(PHTipp)2}] (Cp′ = η5‐C5MeH4, Tipp = 2,4,6‐Pri3C6H2) Cp′2ZrCl(PHTipp)] ( 1 ) (Cp′ = η5‐C5MeH4, Tipp = 2,4,6‐Pri3C6H2) reacts with methyl formate with insertion and substitution to give Cp′2ZrCl{OCH(PHTipp)2}] ( 2 ). 2 was characterized spectroscopically (1H, 31P NMR, IR, MS) and by X‐ray structure determination. Only the meso‐trans isomer is present in the solid state. |
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Keywords: | Zirconium Zirconocene phosphanido complex Insertion reaction |
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