Na3RuD7 – Synthese und Struktur |
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Authors: | W. Bronger,T. Sommer,L. Swinder,P. Mü ller |
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Abstract: | Na3RuD7 – Synthesis and Structure Na3RuD7 was synthesized by the reaction of sodium deuteride with ruthenium powder under a hydrogen pressure of 6000 bar at 900 K. X‐ray investigations on powdered samples and elastic neutron diffraction experiments led to the atomic arrangement (space group: P42/mnm), which is characterized by isolated [RuD7]‐anions. The coordination polyhedron formed by the seven deuterium ligands can be described as a distorted pentagonal bipyramide. |
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Keywords: | Metal hydrides High pressure synthesis Crystal structure Neutron diffraction |
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