| Abstract: | The Formation of an Amine Stabilized Co2S4 Heterocycle: Structure and Synthesis of a Rare Example of a Double μ‐η1 : η1 Disulfido Bridged Binuclear Metal Complex Treatment of Co(BPh4)2 · 6 MeCN and Co(ClO4)2 · 6 MeCN with S22– or S42– in the presence of the macrocyclic tetraaza ligand 1,4,8,12‐tetraazacyclopentadecane ([15]aneN4) afforded the new binuclear cobalt sulfur compounds [Co(μ‐S2)([15]aneN4)]2[BPh4]2 ( 1 ) and [Co(μ‐S2)([15]aneN4)]2[ClO4]2 ( 2 ), respectively, in which two cobalt atoms are bridged by two μ‐η1 : η1 disulfido groups forming six‐membered Co2S4 heterocycles. |
