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Plume Deposits from Bipropellant Rocket Engines: Methylhydrazinium Nitrate and N,N‐Dimethylhydrazinium Nitrate
Authors:Olivier de Bonn  Anton Hammerl  Thomas M Klaptke  Peter Mayer  Holger Piotrowski  Helmut Zewen
Abstract:The predominant species in the plume residues resulting from the incomplete combustion of methylhydrazine (MMH)/N,N‐dimethylhydrazine (UDMH) and N2O4 (NTO) in rocket engines are methylhydrazinium and N,N‐dimethylhydrazinium nitrate. Both compounds were synthesized, characterized and their crystal structures were determined. The thermal, shock and friction sensitivity of these compounds was investigated. For both compounds the products formed in their thermal decompositions were determined.
Keywords:Fuel  High energy materials  Monomethyl hydrazine (MMH)  Hydrazinium nitrate  Rocket propulsion
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