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Gallium Zigzag Chains as an Ordering Principle in η5‐2,5‐di‐(t‐butyl) phospholylgallium(I) |
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| Authors: | Jaroslaw Chojnacki,Elke Baum,Ingo Krossing,Duncan Carmichael,Francois Mathey,Hansgeorg Schnö ckel |
| Abstract: | The solid state structure of η5‐2,5‐di‐(t‐butyl)phospholylgallium(I) 1 was determined by X‐ray diffraction at 190 K. The molecules of 1 are partly organized in a for sandwich complexes new type of structure: a Ga zigzag chain in which the aromatic phospholyl rings alternate on both sides of the chain. |
| Keywords: | Gallium Sandwich complexes Phosphorus ligands |