Abstract: | The synthesis and characterization of several azide salts of organic hydrazinium derivatives is reported. The crystal structures of N‐amino‐1‐azoniacycloheptane azide, morpholinium azide, N,N‐dibenzylhydrazine and phenylhydrazinium azide phenylhydrazinate were determined. The thermal, shock and friction sensitivity of these compounds was investigated. For several compounds the products formed in the explosive decomposition were determined. |