Abstract: | CpR(OC)Mo(μ‐η2:2‐P2)2FeCpR′] as Educt for Heterobimetallic Dinuclear Clusters with P2 and CnRnP4‐n Ligands (n = 1, 2) The cothermolysis of CpR(OC)Mo(μ‐η2:2‐P2)2FeCpR′] ( 1 ) and tBuC≡P ( 2 ) as well as PhC≡CPh ( 3 ) affords the heterobimetallic triple‐decker like dinuclear clusters (Cp'''Mo)(Cp*′Fe)(P3CtBu)(P2)] ( 4 ), Cp''' = C5H2tBu3‐1,2,4, Cp*′ = C5Me4Et, and (Cp*Mo)(Cp*Fe)(P2C2Ph2)(P2)] ( 5 ) with a bridging tri‐ and diphosphabutadiendiyl ligand. 4 and 5 have been characterized additionally by X‐ray crystallography. |