Multiisotopic modeling of fragmentation ion patterns in mass spectra of organometallic and coordination compounds

Investigation of hardly interpretable complex patterns can lead to an explanation of details of fragmentation and, therefore, the identification of ion clusters can be a significant procedure of mass spectra interpretation. The modeling presented remains a simple tool for mass spectra interpretation and determination of parameters of complex cluster components. Good adjustment of model to experimental data suggests that such components must be considered in the pattern interpretation; approach results in the model fits within a 1% precision for the cluster of two or more components. Applications of the Multiisotopic Modeling of Fragmentation Ion Patterns (MMFIP method) are presented for bis(dibutyldithiophosphate)‐zinc(II)‐[(C₄H₉O)₂PS₂]₂Zn, 1′,1‴‐dibenzylbiferrocene‐C₃₄H₃₀Fe₂ and 1,1′,2,2′,3,3′‐hexachloroferrocene‐C₁₀H₄Cl₆Fe as examples. It seems that the isotopic cluster modeling based on the least squares method can be a helpful aid for determination of the complex pattern components. © 2001 John Wiley & Sons, Inc. J Comput Chem 22: 354–365, 2001