Abstract: | Coordination Chemistry of P‐rich Phosphanes and Silylphosphanes. XXIV. Formation and Structure of μ‐(1,2 : 2‐η‐tBu2P–P){Mo(CO)2cp′}2] cp′Mo(CO)2]2 (cp′ = C5H4tBu) reacts with tBu2P–P=P(Me)tBu2 to yield the compound μ‐(1,2 : 2‐η‐tBu2P–P){Mo(CO)2cp′}2], which crystallizes in the space group P212121 with a = 1202.42(7), b = 1552.48(8), and c = 1765.3(1) pm. |