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Synthesis of alkenylsilanes via palladium(0)-catalyzed silylation of alkenyl iodides with hydrosilane
Authors:Miki Murata   Shinji Watanabe  Yuzuru Masuda  
Affiliation:

aDepartment of Materials Science, Kitami Institute of Technology, Kitami 090-8507, Japan

Abstract:Various alkenyl iodides were silylated with hydrosilanes in the presence of KOAc and a catalytic amount of Pd2(dba)3·CHCl3 to afford the corresponding regio- and stereodefined (E)-alkenylsilanes in high yields.
Keywords:hydrosilane   alkenylsilane   alkenyl halides   palladium catalyst   coupling reactions
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