Pentacoordination of boron, carbon, aluminum, and silicon atoms in organic compounds: Anab initio study |
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Authors: | R M Minyaev A G Starikov |
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Institution: | (1) Institute of Physical and Organic Chemistry, Rostov State University, 194/2 prosp. Stachki, 344090 Rostov-on-Don, Russian Federation |
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Abstract: | Pentacoordination of boron, carbon, aluminum, and silicon atoms in bicyclic organic compounds of the pentalene type was studied
using theab initio RHF/6-31G** and MP2(full)/6-31G** methods. It was shown that the ability of the atom to form pentacoordinate structures increases on going from B to Al and
from C to Si atom,i.e. as the number of the element of Groups IIIA and IVA of the periodic system increases. At the same time, the reverse tendencies
are observed in the 2nd and 3rd periods of the periodic system,viz., the ability of the atom to form pentacoordinate structures increases on going from C to B and from Al to Si atom.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1238–1245, July, 1999. |
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Keywords: | ab initio quantum-chemical calculations nucleophilic substitution pentacoordination of boron carbon aluminum and silicon |
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