| Synthesis and Molecular Structure of 1,5,1 ＇,5 ＇-Tetraphenyl- 1H, 1H ＇-3,3 ＇- dialkylthio-bi- 1,2,4-t riazole |
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| 引用本文： | 姜文清,刘天宝,邹建平,张勇.Synthesis and Molecular Structure of 1,5,1 ＇,5 ＇-Tetraphenyl- 1H, 1H ＇-3,3 ＇- dialkylthio-bi- 1,2,4-t riazole[J].结构化学,2007,26(4):445-449. |
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| 作者姓名： | 姜文清 刘天宝 邹建平 张勇 |
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| 作者单位： | Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering Suzhou University，Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering Suzhou University，Department of Chemistry Chizhou Teachers College Chizhou 247100 China，Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering Suzhou University，Key Laboratory of Organic Synthesis of Jiangsu Province College of Chemistry and Chemical Engineering Suzhou University，Jiangsu 215006 China，Jiangsu 215006 China，Jiangsu 215006 China，Jiangsu 215006 China |
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| 基金项目： | 江苏省重点实验室基金
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安徽省自然科学基金 |
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| 摘 要： | The title compound 1,5,1',5'-tetraphenyl-1H,1H'-3,3'-dialkylthio-bi-1,2,4-tri- azole (2, C28H20N6S2, Mr = 504.62) was prepared by the reaction of 1-benzoyl-3-phenylamino- thiourea 1 and Mn(OAc)3·2H2O in acetic acid under microwave irradiation. The crystal is of monoclinic, space group P21/c with a = 11.3931(10), b = 16.5787(14), c = 26.470(2) , β = 98.274(2)o, Z = 8, V = 4947.8(8) 3, Dc = 1.355 g/cm3, μ(MoKα) = 0.245 mm-1, F(000) = 2096, the final R = 0.0583 and wR = 0.1502 for 8705 observed reflections (I > 2σ(I)). X-ray analysis reveals that the title compound is 1,5,1',5'-tetraphenyl-1H,1H'-3,3'-dialkylthio-bi-1,2,4-triazo- le, and its formation mechanism was proposed.
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| 关 键 词： | 三唑 l-苯甲酰-3-苯氨基硫脲 合成 分子结构 |
Synthesis and Molecular Structure of 1,5,1',5'-Tetraphenyl-1H,1H'-3,3'-dialkylthio-bi-1,2,4-triazole |
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| JIANG Wen-Qing,LIU Tian-Bao,ZOU Jian-Ping,ZHANG Yong.Synthesis and Molecular Structure of 1,5,1'''',5''''-Tetraphenyl-1H,1H''''-3,3''''-dialkylthio-bi-1,2,4-triazole[J].Chinese Journal of Structural Chemistry,2007,26(4):445-449. |
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| Authors: | JIANG Wen-Qing LIU Tian-Bao ZOU Jian-Ping ZHANG Yong |
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| Institution: | 1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Jiangsu 215006, China
2. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Jiangsu 215006, China;Department of Chemistry, Chizhou Teachers College, Chizhou 247100, China |
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| Abstract: | The title compound 1,5,1',5'-tetraphenyl-1H,1H'-3,3'-dialkylthio-bi-1,2,4-triazole (2, C28H20N6S2, Mr=504.62) was prepared by the reaction of 1-benzoyl-3-phenylaminothiourea 1 and Mn(OAc)3·2H2O in acetic acid under microwave irradiation. The crystal is of monoclinic, space group P21/c with a=11.3931(10), b=16.5787(14), c=26.470(2) (A), β=98.274(2)°, Z=8, V=4947.8(8) (A)3, Dc=1.355 g/cm3, μ(MoKα) (A) 0.245 mm-1, F(000)=2096, the final R=0.0583 and Wr=0.1502 for 8705 observed reflections (Ⅰ ＞ 2σ(Ⅰ)). X-ray analysis reveals that the title compound is 1,5,1',5'-tetraphenyl-1H,1H'-3,3'-dialkylthio-bi-1,2,4-triazole, and its formation mechanism was proposed. |
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| Keywords: | triazole 1-benzoyl-3-phenylaminothiourea crystal structure Molecular Structure formation mechanism analysis final space group crystal acetic acid microwave irradiation reaction compound |
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