| 手性联萘酚的多胺缀合物的合成与表征 |
| |
| 引用本文： | 焦书燕,马金飞,杨丽,徐括喜.手性联萘酚的多胺缀合物的合成与表征[J].化学研究,2010,21(4):52-54,57. |
| |
| 作者姓名： | 焦书燕 马金飞 杨丽 徐括喜 |
| |
| 作者单位： | 河南大学,化学化工学院,精细化学与工程研究所,河南,开封,475004 |
| |
| 基金项目： | 国家自然科学基金，河南省教育厅基金 |
| |
| 摘 要： | 以N1-氨基丁基-N1,N4-二叔丁氧羰基-1,4-丁二胺和手性甲酰基联萘酚为原料,经缩合后用NaBH4还原,产物提纯后脱保护,得到目标产物S-6和R-6,所得化合物的结构均经IR、1H NMR、13C NMR和MS测试确认.
|
| 关 键 词： | 联萘酚 多胺 手性缀合物 合成 表征 |
Synthesis and Characterization of Chiral Conjugate of Bisnaphthol and Polyamine |
| |
| JIAO Shu-yan,MA Jin-fei,YANG Li,XU Kuo-xi.Synthesis and Characterization of Chiral Conjugate of Bisnaphthol and Polyamine[J].Chemical Research,2010,21(4):52-54,57. |
| |
| Authors: | JIAO Shu-yan MA Jin-fei YANG Li XU Kuo-xi |
| |
| Institution: | (Institute of Fine Chemical and Engineering,College of Chemistry and Chemical Engineering,Henan University,Kaifeng 475004,Henan,China) |
| |
| Abstract: | Conjugate of chiral bisnaphthol and polyamine was synthesized via condensed polymerization of N1-aminobutyl-N1,N4-di-tert-butoxycarbonylbutane-1,4-diamine and 3,3′-diformyl-2,2′-dihydroxy-1,1′-binaphthyl as the start materials in association with reduction of crude product by NaBH4 and purification for deprotection.The structures of the compounds were confirmed by infrared spectrometry（IR）,nuclear magnetic resonance spectroscopy（1H NMR,13C NMR） and mass spectrometry（MS）. |
| |
| Keywords: | binaphthol polyamine chiral conjugate synthesis characterization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
