Modeling liquid thermal explosion reactor containing <Emphasis Type="Italic">tert</Emphasis>-butyl peroxybenzoate |
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Authors: | Chun-Ping Lin Jo-Ming Tseng Yi-Ming Chang Shang-Hao Liu Yen-Chun Cheng Chi-Min Shu |
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Institution: | (1) Department of Health and Nutrition Biotechnology, College of Health Science, Asia University, 500, Lioufeng Rd., Wufeng, Taichung, 41354, Taiwan, ROC;(2) Institute of Safety and Disaster Prevention Technology, Central Taiwan University of Science and Technology, 666, Buzih Rd., Beitun District, Taichung, 40601, Taiwan, ROC;(3) Process Safety and Disaster Prevention Laboratory, Department of Safety, Health, and Environmental Engineering, National Yunlin University of Science and Technology (NYUST), 123, University Rd., Sec. 3, Douliou, 64002, Yunlin, Taiwan, ROC; |
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Abstract: | This study investigated the role played by green thermal analysis technology in promoting the use of resources, preventing
pollution, reducing energy consumption and protecting the environment. The chemical tert-butyl peroxybenzoate (TBPB) has been widely employed in the petrifaction industries as an initiator of polymerization formation
agent. This study established the thermokinetic parameters and thermal explosion hazard for a reactor containing TBPB via
differential scanning calorimetry (DSC). To simulate thermokinetic parameters, a 5-ton barrel reactor of liquid thermal explosion
model was created in this study. The approach was to develop a precise and effective procedure on thermal decomposition, runaway,
and thermal hazard properties, such as activation energy (E
a), control temperature (CT), critical temperature (TCR), emergency temperature (ET), heat of decomposition (∆H
d), self-accelerating decomposition temperature (SADT), time to conversion limit (TCL), total energy release (TER), time to maximum rate under isothermal condition (TMR
iso), etc. for a reactor containing TBPB. Experimental results established the features of thermal decomposition and huge size
explosion hazard of TBPB that could be executed as a reduction of energy potential and storage conditions in view of loss
prevention. |
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