Investigation of the electronic vibrational structure of furan by REMPI |
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| Authors: | Philis J G |
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| Institution: | Department of Physics, University of Ioannina, Dourouti, GR451110 Ioannina, Greece. iphilis@uoi.gr |
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| Abstract: | Resonance-enhanced multiphoton ionization (REMPI) has been applied to detect the hot bands as well as the cold bands of the 1a2-->-->3dxy(1A1) Rydberg transition of furan (jet-cooled, mass-analyzed). Based on the unambiguous assignment of the hot bands, a complete vibronic analysis is given for the cold bands of this transition (up to 4600 cm(-1) above the origin). This analysis can be used for the interpretation of the vibrational structure in the X 2A2 photoelectron band. The energy ordering of the five 3d Rydberg states is 1A2 approximately 2A2
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| Keywords: | Furan Rydberg states Vibrational structure REMPI Photodissociation CH |
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