| 水合二(对叔丁基苄基)二氯化锡的合成及晶体结构 |
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| 引用本文： | 张复兴,邝代治,王剑秋,冯泳兰,许志锋,陈志敏.水合二(对叔丁基苄基)二氯化锡的合成及晶体结构[J].无机化学学报,2007,23(7):1230-1233. |
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| 作者姓名： | 张复兴 邝代治 王剑秋 冯泳兰 许志锋 陈志敏 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省教育厅资助项目;湖南省自然科学基金 |
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| 摘 要： | The organotin hydration di(p-tert-butylbenzyl)tin dichloride has been synthesized. The crystal structure of complex has been determined by X-ray diffraction. The crystal belongs to orthorhombic space group Pmma with a=1.108 4(2) nm, b=3.492 0(7) nm, c=0.626 36(12) nm, V=2.424 3(8) nm3, Z=4, Dc=1.376 g·cm-3, μ(Mo Kα)=12.82 cm-1, F(000)=1 024, R1=0.085 9, wR=0.225 7. The bond lengths of Sn-Cl are 0.236 0(2) nm and 0.250 8(4) nm, the Sn-C is 0.212 1(11) nm, the Sn-O is 0.233 2(12) nm. The tin rendered five-coordinate in a distorted trigonal bipyramidal configuration. CCDC: 648618.
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| 关 键 词： | 二(对叔丁基苄基)二氯化锡 水合 合成 晶体结构 |
| 文章编号： | 1001-4861（2007）07-1230-04 |
| 修稿时间： | 2006-12-042007-05-10 |
Synthesis and Crystal Structure of Hydration di(p-tert-butylbenzyl)tin Dichloride |
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| ZHANG Fu-Xing,KUANG Dai-Zhi,WANG Jian-Qiu,FENG Yong-Lan,XU Zhi-Feng and CHEN Zhi-Ming.Synthesis and Crystal Structure of Hydration di(p-tert-butylbenzyl)tin Dichloride[J].Chinese Journal of Inorganic Chemistry,2007,23(7):1230-1233. |
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| Authors: | ZHANG Fu-Xing KUANG Dai-Zhi WANG Jian-Qiu FENG Yong-Lan XU Zhi-Feng and CHEN Zhi-Ming |
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| Institution: | Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 and Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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| Abstract: | |
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| Keywords: | di(p-tert-butylbenzyl)tin dichloride hydration synthesis crystal structure |
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